I hate it when people bring up the Monty Hall problem because I can never remember why it works and I have to go look it up and work through it in my head and it's all very unpleasant.
Anyway having just done that, here's my explanation. Start from the assumption that the door you picked at random isn't the right door. That means one of the two other doors has the car. Monty cannot open the door with the car, and your initial choice was incorrect, so he must open the door in the remaining pair of doors that doesn't have the car.
But if your initial guess was wrong, then Monty is effectively showing you where the car is. There are three doors, you picked one that had a goat. He showed the other goat. The car is behind the door he didn't open and you didn't pick.
Said another way, if your initial guess was wrong, switching will give you the car. Your chance of being wrong initially is 67%, so you have a 67% chance of winning by switching vs the 33% chance of your initial guess being right.
